Duelist - derke
sentinel - alfajer
flex - xeppaa
initiator - leo
smokes - jakee
igling - boast
coach - d00mbros
hmmm the mini rate has always been hard for me. While he has coached b2b winners everything ive heard from ppl with insider knowledge on FNC makes me think he plays a much more supportive role and boaster takes on a shit ton of the responsibilities we would typically think of as coaches (bringing in new strats doing research on counter strats and even helping with a lot of the scouting and having big sway in roster moves). In terms of pure "this coach transformed a shit team into a good one" I think potter edges him out.
Not saying mini is bad just that he gets slightly overrated since the team is good and he has less impact than ppl think.
Duelist - lots of great answers, though I would put Jingg or derke here. Part of me wants to even say Cryo but his team is shite around him
Sentinel - nats or alfa, no other
Initiator - D4v41, does not get enough love
smokes - s0m
IGL - saadhaak
Flex - forsaken
Coach - Legija
BONUS
Best commentary duo - Doug and Balla
Duelist - derke
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aspas better