As of my knowledge cutoff in September 2021, Valorant had not been released yet, so it's challenging to determine the top Valorant players of all time. However, I can provide you with a list of notable Valorant players who were prominent during the early stages of the game. Keep in mind that the Valorant esports scene is constantly evolving, and new talents may have emerged since then. Here are five players who were highly regarded at the time:

Adil "ScreaM" Benrlitom: Known for his exceptional aim and mechanical skill, ScreaM was one of the standout players during Valorant's early days. He played for Team Liquid and showcased remarkable precision and aim.

Jay "sinatraa" Won: Previously a professional Overwatch player, sinatraa transitioned to Valorant and quickly established himself as one of the top talents. He played for Sentinels and was highly praised for his versatility and game sense.

Oscar "Mixwell" Cañellas Colocho: A former professional Counter-Strike: Global Offensive (CS:GO) player, Mixwell successfully made the switch to Valorant. He played for G2 Esports and was known for his excellent AWP (sniper rifle) skills.

Matthew "WARDELL" Yu: A prominent North American player, WARDELL played for TSM (Team SoloMid) and was recognized for his exceptional operator (sniper) play. His precise aim and clutch potential made him a formidable opponent.

Kevin "Ex6TenZ" Droolans: Ex6TenZ, a former CS:GO player, made his mark in the early Valorant scene. He showcased his tactical prowess and leadership skills while playing for Team Liquid.

Please note that this list reflects the state of the Valorant esports scene up until September 2021. As the game progresses and more tournaments take place, new players may emerge as top performers.