how do
Here's what I have set in Nvidia Profile Inspector for Valorant. Enhance may potentially have better latency than override(1 frame) according to an Nvidia doc I read somewhere, so I prefer that.:
You have to set these two files to read only(right click > properties > read only) after applying changes in Nvidia profile inspector, or it will reset the transparency supersampling option when you start the game:
4x or 8x TRSGSS in my game it makes the agents look like they're covered in baby oil. 8x Transparency Supersampling looks worse to me than 2x Transparency Sparse Grid Supersampling, so I use 2x Transparency SGSS.
As far as I can tell, Tranparency Multisampling doesn't work at all.
32xS is a lot, if it pegs your GPU, try 8x Multisampling(8xQ), 8xS or 4x. The CSAA options don't work since I think the GTX 9xx series. Maybe even the GTX 7xx. They just turn on multisampling, but worse. (8xQ looks better than 32x CSAA)
MFAA helps to my eye, so I turn that on too.