The NA curse only applies when all team members and coach have not been to a valo lan before. Asuna and coach seangares have been to lan before so the curse doesn't apply to them. Also 100T as an org has been to a lan before.
I don't see them getting grouped unless they fall into a "group of death" fundamentally they're a great team and with Asuna's LAN experience and the 100T coaching staff, I see them making it out, but who knows, anything is possible.