It’s really base on the map and who is playing which role but I think it’s generally
Controller > Initiator > Duelist > Sentinel
Controller- Extremely hard to win without one
Initiator- Hard to win without one, but the role can be fulfilled replaced by certain non initiator agents if utility is used well
Duelist- A good duelist can single-handedly win you games, but if a duelist is replaced by an initiator on certain map, you’ll honestly be fine.
Sentinel- A good sentinel can also single-handedly win you games, it’s a must play on heavy attack sided maps or else its belt to ass.
all 4 are important but this is my opinion