In my humble view, from just a fan who has been following the BR scene since the beginning, I can't envision a team that I'm 100% sure would work, but I have names in mind, maybe a little different from most...
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Mwzera (Duelist) - Destroys with any duelist, despite playing mostly just as Raze in championships. The few times I saw him playing Reyna, I almost left crying with happiness.
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NZR (Initiator) - One of the smartest players and skilled on the scene, (also using the theory that he needs an Argentine for the team to succeed)
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RglM (Smoke) - Following LOUD's logic of getting a highly skilled player who was always top frag even playing Smoke, it seems to be the best option in this sense.
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Bezn1 (Sentinel) - Everyone saw what he did for NiP at the Masters, being one of the most clutches and standing out on that team. His aim is different.
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Gaabx (Flex) - This is probably one of the ones that will disagree with me the most, but he always played Sage and Viper well even though he was main Jett, so I think he would excel very well in that role. The guy literally carried that tired Sharks team to the Iceland Masters 2021, he has a certain star.
I don't see how to fit the Heat or QCK into a team like this without forcing the bar, I think this one above would be the most complete team. MIBR is surprising a lot in this beginning of VCTBR, but I still don't see anyone standing out as much.